With the collaboration of Iran Polymer Society
Catalysis
Effects of Ti/Mg molar ratio on bi-supported SiO2/MgCl2 (ethoxide type)/TiCl4 catalysts in ethylene homopolymerization and ethylene/1-hexene copolymerization

Liang Zhu; Xuelian He; Ruihua Cheng; Zhen Liu; Ning Zhao; Boping Liu

Volume 5, Issue 1 , January 2018, , Pages 1-13

https://doi.org/10.22063/poj.2017.1470

Abstract
  SiO2/MgCl2 (ethoxide type)/TiCl4 Ziegler-Natta catalysts for use in ethylene polymerization and ethylene/1-hexene copolymerization have been prepared using silica with a supported layer of magnesium ethoxide (Mg(OEt)2) as a catalyst precursor, followed by treating with TiCl4 at different Ti/Mg ...  Read More

Catalysis
Probing into morphology evolution of magnesium ethoxide particles as precursor of Ziegler-Natta catalysts

Goond Hongmanee; Patchanee Chammingkwan; Toshiaki Taniike; Minoru Terano

Volume 3, Issue 1 , January 2016, , Pages 47-57

https://doi.org/10.22063/poj.2016.1266

Abstract
  Mg(OEt)2 with spherical morphology is one of the most important precursors for the preparation of industrial Ziegler-Natta catalysts. In the present article, morphology evolution of Mg(OEt)2 particles is studied in the course of the synthesis. The morphology of Mg(OEt)2 particles is observed throughout ...  Read More