Finely-tuned strength-toughness balance of PPR/UHMWPE blends via shear-enhanced crystal orientation and cocrystal-locked UHMWPE particles

Document Type : Original research

Authors

1 Qinghai Provincial Drug inspection and Testing Institute, Xi’ning, 810016, China

2 Qinghai Institute of Medical Device Supervision and Testing, Xi’ning, 810016, China

3 NMPA Key Laboratory for Quality Control of TCM(Tibetan Medicine, Xi’ning, 810016, China

Abstract

The presence of ultrahigh molecular weight species in polymer melt facilitates the formation of highly-oriented crystalline structures and favors the improvement of mechanical properties. However, due to the random copolymer chain architecture, it is difficult to obtain high orientation of crystals for polypropylene random copolymers (PPR). In this work, two binary blends including polypropylene (PP)/ultrahigh molecular weight polyethylene (UHMWPE) and polypropylene random copolymer (PPR)/UHMWPE were fabricated via solution blending and subsequent melt shear through mini-injection molding. It was found that highly-oriented crystalline structure forms under shear flow in both blend series. The tensile strength of PP blends increased from 38.3MPa to 43.8MPa while the PPR blends showed a more significant property enhancement and increased from 32.5MPa to 38.1MPa. Importantly, PPR shows an increased miscibility with UHMWPE in comparison with PP due to the existence of ethylene segments. The tensile toughness of PPR samples was greatly maintained especially for blends with small addition of UHMWPE, which may be ascribed to the crack-suppression effect originated from well-dispersed UHMWPE domains (particle size < 0.50 μm) locked by the co-crystal structures between PPR segments and molecularly mixed PE chains.

Graphical Abstract

Finely-tuned strength-toughness balance of PPR/UHMWPE blends via shear-enhanced crystal orientation and cocrystal-locked UHMWPE particles

Highlights

  1. Low addition of UHMWPE is inclined to be miscible with the PP matrix.
  2. Phase separation occurs at high addition of UHMWPE.
  1. The co-crystal structure locks UHMWPE domains into smaller size.
  2. Orientated crystal leads to balanced mechanical strength and toughness for PPR.

Keywords



Articles in Press, Accepted Manuscript
Available Online from 09 July 2024
  • Receive Date: 11 April 2024
  • Revise Date: 19 June 2024
  • Accept Date: 06 July 2024