Document Type : Original research
Authors
1 Department of Chemical Engineering and Materials Science, Amrita School of Engineering, Coimbatore, Amrita Vishwa Vidyapeethaam, Coimbatore, India
2 Department of Chemical Engineering and Materials Science, Amrita School of Engineering, Coimbatore, Amrita Vishwa Vidyapeetham, India
Abstract
Nano, micro and hybrid filler-reinforced polypropylene (PP) composites were prepared via melt compounding technique using a twin screw extruder. The nano scale MWCNTs and micro scale glass fibers were used as reinforcements. In addition to the individual effect of nano and micro scale reinforcements in virgin PP, the dual effect of multiscale (MWCNT/glass fiber) fillers was also elucidated. Morphological images revealed the effectiveness of dispersion of the fillers in the matrix and it was observed that the functionalized composites showed increased filler dispersion. The static mechanical properties of the non-functionalized and functionalized samples were compared and the hybrid composite with 2 wt.% MWCNTs showed the highest tensile strength without modulus reduction. The strong bonding between carboxyl-treated MWCNTs and maleic anhydride-grafted PP was well revealed in the FTIR spectra. In hybrid composites, the effect of silane-treated glass fibers was revealed and the siloxane linkages occurred between the glass fiber surface and silanol groups were confirmed by the FTIR spectra.
Keywords
- Dikshit V, Bhudolia SK, Joshi SC (2017) Multiscale polymer composites: A review of the interlaminar fracture toughness improvement. Fibers 5: 38
- Rasana N, Jayanarayanan K, Pavithra R, Nandhini GR, Ramya P, Veeraraagavan AV (2019) Mechanical and thermal properties modeling, sorption characteristics of multiscale (multiwalled carbon nanotubes/glass fiber) filler reinforced polypropylene composites. J Vinyl Addit Technol 25: E94-107
- Jeevanandam J, Barhoum A, Chan YS, Dufresne A, Danquah MK (2018) Review on nanoparticles and nanostructured materials: history, sources, toxicity and regulations. Beilstein J Nanotechnol 9:1050-1074
- Mishnaevsky Jr L, Dai G (2014) Hybrid and hierarchical nanoreinforced polymer composites: Computational modelling of structure–properties relationships. Compos Struct 117:156-168
- Ali A, Andriyana A (2020) Properties of multifunctional composite materials based on nanomaterials: A review. RSC Adv 10: 16390- 16403
- Fu S, Sun Z, Huang P, Li Y, Hu N (2019) Some basic aspects of polymer nanocomposites: A critical review. Nano Mater Sci 1: 2-30
- Müller K, Bugnicourt E, Latorre M, Jorda M, Echegoyen Sanz Y, Lagaron JM, Miesbauer O, Bianchin A, Hankin S, Bölz U, Perez G (2017) Review on the processing and properties of polymer nanocomposites and nanocoatings and their applications in the packaging, automotive and solar energy fields. Nanomater 7: 74
- Mittal G, Rhee KY, Mišković-Stanković V, Hui D (2018) Reinforcements in multi-scale polymer composites: processing, properties, and applications. Compos Part B-Eng 138: 122-139
- Silva F, Njuguna J, Sachse S, Pielichowski K, Leszczynska A, Giacomelli M (2013) The influence of multiscale fillers reinforcement into impact resistance and energy absorption properties of polyamide 6 and polypropylene nanocomposite structures. Mater Design 50: 244-252
- Rasana N, Jayanarayanan K (2019) Experimental and micromechanical modeling of fracture toughness: MWCNT-reinforced polypropylene/ glass fiber hybrid composites. J Thermoplast Compos Mater 32:1031-1055
- McCrary-Dennis MC, Okoli OI (2012) A review of multiscale composite manufacturing and challenges. J Reinf Plastics Compos 31: 1687-1711
- Qiu J, Zhang C, Wang B, Liang R (2007) Carbon nanotube integrated multifunctional multiscale composites. Nanotechnology 18: 275708
- Pedrazzoli D, Pegoretti A (2014) Hybridization of short glass fiber polypropylene composites with nanosilica and graphite nanoplatelets. J Reinf Plast Compos 33: 1682-1695
- Enrique-Jimenez P, Quiles-Díaz S, Salavagione H J, Fernández-Blázquez J P, Monclús M A, de Villoria R G, Gómez-Fatou M A, Ania F, Flores A (2019) Nanoindentation mapping of multiscale composites of graphene-reinforced polypropylene and carbon fibres. Compos Sci Technol 169: 151-157
- Gonzalez-Chi P I, Rodríguez-Uicab O, Martin- Barrera C, Uribe-Calderon J, Canché-Escamilla G, Yazdani-Pedram M, May-Pat A, Avilés F (2017) Influence of aramid fiber treatment and carbon nanotubes on the interfacial strength of polypropylene hierarchical composites. Compos Part B-Eng 122: 16-22
- Rahmanian S, Suraya AR, Othman RN, Zahari R, Zainudin ES (2015) Growth of carbon nanotubes on silica microparticles and their effects on mechanical properties of polypropylene nanocomposites. Mater Design 69: 181-189
- Pandey G, Thostenson ET (2012) Carbon nanotube-based multifunctional polymer nanocomposites. Polym Rev 52: 355-416
- Speranza G (2019) The role of functionalization in the applications of carbon materials: An overview. C-J Carbon Res 5: 84
- Ma P C, Siddiqui N A, Marom G, Kim J K (2010) Dispersion and functionalization of carbon nanotubes for polymer-based nanocomposites: A review. Compos Part A- Appl S 41: 1345-1367
- Mittal G, Dhand V, Ryu JI, Rhee KY, Kim HJ, Jung DH (2015) Fabrication of modified MMT/ glass/vinylester multiscale composites and their mechanical properties. J Nanomater 16: 326
- Karsli NG, Yesil S, Aytac A (2014) Effect of hybrid carbon nanotube/short glass fiber reinforcement on the properties of polypropylene composites. Compos Part-B Eng 63:154-160
- Oromiehie A, Ebadi-Dehaghani H, Mirbagheri S (2014) Chemical modification of polypropylene by maleic anhydride: Melt grafting, characterization and mechanism. Int J Chem Eng Appl 5: 117
- Girei SA, Thomas SP, Atieh MA, Mezghani K, De SK, Bandyopadhyay S, Al-Juhani A(2012) Effect of–COOH functionalized carbon nanotubes on mechanical, dynamic mechanical and thermal properties of polypropylene nanocomposites. J Thermoplast Compos Mater 25: 333-350
- Jin SH, Kang CH, Yoon KH, Bang DS, Park YB (2009) Effect of compatibilizer on morphology, thermal, and rheological properties of polypropylene/functionalized multi-walled carbon nanotubes composite. J Appl Polym Sci 111: 1028-1033
- Wah CA, Choong LY, Neon GS (2000) Effects of titanate coupling agent on rheological behaviour, dispersion characteristics and mechanical properties of talc filled polypropylene. Eur Polym J 36: 789-801
- Akil HM, Lily N, Razak JA, Ong H, Ahmad ZA (2006) Effect of various coupling agents on properties of alumina-filled PP composites. J Reinf Plast Compos 25: 745-759
- Barus S, Zanetti M, Lazzari M, Costa L (2009) Preparation of polymeric hybrid nanocomposites based on PE and nanosilica. Polymer 50: 2595- 2600
- Arbelaiz A, Fernández B, Cantero G, Llano-Ponte R, Valea A, Mondragon I (2005) Mechanical properties of flax fibre/polypropylene composites. Influence of fibre/matrix modification and glass fibre hybridization. Compos A Appl Sci Manuf 36:1637-1644
- Cui J, Wang S, Wang S, Li G, Wang P, Liang C (2019) The effects of strain rates on mechanical properties and failure behavior of long glass fiber reinforced thermoplastic composites. Polymers 11: DOI: 10.3390/polym11122019
- Mittal G, Rhee KY, Mišković-Stanković V, Hui D (2018) Reinforcements in multi-scale polymer composites: processing, properties, and applications. Compos Part B-Eng 138: 122-139