Document Type : Original research
Authors
1 Faculty of Mechanics and Energy, Shahid Beheshti University, Tehran, Iran
2 Faculty of Mechanical Eng., Shahid Rajaee Teacher Training University, Tehran, Iran
3 Iran Polymer and Petrochemical Institute, Tehran, Iran
Abstract
Polyamide 6 / nitrile butadiene rubber / nanoclay (PA6/NBR/clay) nanocomposite has gathered wide acceptance in industry. Laser welding, as a fabrication method, is applied to welding of polymer nanocomposites. In this study, the input parameters (clay (Closite 30B) content, laser power, scan velocity and stand-off-distance) are varied to achieve the best responses (tensile strength of welds). Response surface methodology (RSM) is utilized to investigate the effect of input parameters on mechanical properties. Morphology and tensile properties of nanocomposites were observed with scan electron microscopy (SEM), transmission electron microscopy (TEM) and tensile test. The results demonstrated that increasing the clay content from 1 to 5%wt and stand-off-distance from 4 to 8 mm decreased tensile strength of welds about 15% and 5%, respectively. The tensile strength of PA6/NBR composite is 25.6, whereas the prediction models showed that under optimal conditions of laser power of 105 W, scan velocity of 300 mm/min and stand-off-distance of 4 mm, the maximum tensile strength of PA6/NBR nanocomposite with 1, 3 and 5 % nanoclay are 27.2 MPa, 27.6 MPa and 24.7 MPa, respectively. These tensile strengths are about 99, 89 and 73% of the strength of these nanocomposites before welding.
Keywords
Main Subjects
- Cheremisinoff P (1997). Handbook of engineering polymeric materials CRC Press.
- Gomari S, Ghasemi I, Karrabi M, Azizi H (2015) An investigation on non-isothermal crystallization behavior and morphology of polyamide 6/ poly (ethylene-co-1-butene)-graft-maleic anhydride/organoclay nanocomposites. Polyolefins J 2: 99-108
- Nakhaei M, Arab NM, Naderi G, Gollo MH (2013) Experimental study on optimization of CO2 laser welding parameters for polypropylene-clay nanocomposite welds. J Mech Sci Technol 27: 843-848
- Nakhaei M, Naderi G, Mostafapour A (2016) Effect of processing parameters on morphology and tensile properties of PP/EPDM/organoclay nanocomposites fabricated by friction stir processing. Iran Polym J 25: 179-191
- Taghizadeh E, Naderi G, Dubois C (2010) Rheological and morphological properties of PA6/ECO nanocomposites. Rheol acta 49: 1015-1027
- Mallick S, Kar P, Khatua B (2012) Morphology and properties of nylon 6 and high density polyethylene blends in presence of nanoclay and PE-g-MA. J Appl Polym Sci 123: 1801-1811
- Chakraborty S, Bandyopadhyay S, Ameta R, Mukhopadhyay R, Deuri A (2007) Application of FTIR in characterization of acrylonitrile-butadiene rubber (nitrile rubber). Polym Test 26: 38-41
- Fagundes E, Jacobi MA (2012) PA/NBR TPVs: Crosslink system and properties. Polímeros 22: 206-212
- Mostafapour A, Naderi G, Nakhaei MR (2016) Theoretical models for prediction of mechanical behaviour of the PP/EPDM nanocomposites fabricated by friction stir process. Polyolefins J 4: 99-109
- Mahallati P, Arefazar A, Naderi G (2011) Thermal and morphological properties of thermoplastic elastomer nanocomposites based on PA6/NBR. Iran J Chem Eng 8: 56-65
- Oshinski A, Keskkula H, Paul D (1992) Rubber toughening of polyamides with functionalized block copolymers: 2. Nylon-6, 6. Polymer 33: 284-293
- Paran S, Naderi G, Ghoreishy M (2017) Microstructure and mechanical properties of thermoplastic elastomer nanocomposites based on PA6/NBR/HNT. Polym Composite 38: E451-E461
- Paran SR, Naderi G, Ghoreishy MR (2016) Effect of halloysite nanotube on microstructure, rheological and mechanical properties of dynamically vulcanized PA6/NBR thermoplastic vulcanizates. Soft Mater 14: 127-139
- Bates P, Dyck C, Osti M (2004) Vibration welding of nylon 6 to nylon 66. Polym Eng Sci 44: 760-771
- Nandhini R, Moorthy MK, Muthukumaran S (2017) Effect of welding parameters on microstructure and tensile strength of friction stir welded PA 6, 6 joints. Int Polym Process 32: 416- 424
- Bachmann FG, Russek UA (2002) Laser welding of polymers using high-power diode lasers. In: Photon processing in Microelectronics and Photonics. Proc. SPIE 4637, Photon Processing in Microelectronics and Photonics, (18 June 2002); DOI: 10.1117/12.470660
- Nakhaei M, Arab NM, Naderi G (2013) Application of response surface methodology for weld strength prediction in laser welding of polypropylene/clay nanocomposite. Iran Polym J 22: 351-360
- Mayboudi L, Birk A, Zak G, Bates P (2007) Laser transmission welding of a lap-joint: Thermal imaging observations and three–dimensional finite element modeling. J Heat Transfer Sep 129: 1177-1186
- Naderi G, Mostafapour A, Nakhaei M (2014) Effect of nanoclay and process parameters on weld strength and seam width for CO2 laser welding of polypropylene-clay nanocomposite. 11th Seminar on Polymer Science and Thechnology (ISPST), https://www.civilicacom/ Paper-ISPST11-ISPST11_133.html
- Chen M, Zak G, Bates PJ (2011) Effect of carbon black on light transmission in laser welding of thermoplastics. J Mater Process Technol 211: 43- 47
- Hazrati H, Jahanbakhshi N, Rostamizadeh M (2018) Hydophilic polypropylene microporous membrane for using in a membrane bioreactor system and optimization of preparation conditions by response surface methodology. Polyolefins J 5: 97-109
- Nejabat GR, Nekoomanesh M, Arabi H, Sahehi MH, Zohuri GH, Mortazavi SMM, Ahmadjo S, Miller SA (2015) Study of Ziegler-Natta/ (2-PhInd) 2ZrCl2 hybrid catalysts performance in slurry propylene polymerization. Polyolefins J 2: 73-87
- Mostafapour A, Akbari A, Nakhaei M (2017) Application of response surface methodology for optimization of pulsating blank holder parameters in deep drawing process of Al 1050 rectangular parts. Int J Adv Manufact Technol 91: 731-737
- Acherjee B, Kuar AS, Mitra S, Misra D (2012) Modeling and analysis of simultaneous laser transmission welding of polycarbonates using an FEM and RSM combined approach. Opt Las Technol 44: 995-1006
- Kumar N, Bandyopadhyay A (2017) Simulation of the effects of input parameters on weld quality in laser transmission welding (LTW) using a combined response surface methodology (RSM)- finite element method (FEM) approach. Lasers in Eng 36: 225–243
- Nakhaei MR, Mostafapour A, Naderi G (2017) Optimization of mechanical properties of PP/ EPDM/clay nanocomposite fabricated by friction stir processing with response surface methodology and neural networks. Polym Composite 38: E421-E432
- Taghizadeh E, Naderi G, Razavi-Nouri M (2011) Effects of organoclay on the mechanical properties and microstructure of PA6/ECO blend. Polym Test 30: 327-334
- Hajiabdolrasouli M, Babaei A (2018) Rheological, thermal and tensile properties of PE/nanoclay nanocomposites and PE/nanoclay nanocomposite cast films. Polyolefins J 5: 47-58
- Mostafapour A, Naderi G, Nakhaei MR (2018) Effect of process parameters on fracture toughness of PP/EPDM/nanoclay nanocomposite fabricated by novel method of heat assisted Friction stir processing. Polym Composite 39: 2336-2346
- Bani Mostafa Arab N (2015) Investigation on tensile strength of friction stir welded joints in pp/epdm/clay nanocomposites. Int J Eng 28: 1382-1391
- Ahmadi A, Arab NM, Naderi G, Nakhaei M (2017) Optimization of CO2 laser welding process parameters of PP/EPDM/Clay nanocomposite using response surface methodology. Mech Ind 18: 220
- Mokhtarzadeh A and Benatar A (2004) Experiments in hot plate welding of polypropylene nanocomposite. ANTEC: 1168- 1172
- Ghorbel E, Casalino G, Abed S (2009) Laser diode transmission welding of polypropylene: Geometrical and microstructure characterisation of weld. Mater Des 30: 2745-2751
- Nonhof C (1994) Laser welding of polymers. Polym Eng Sci 34: 1547-1549