Document Type : Original research
Authors
1 Agricultural Engineering Research Institute (AERI), Agricultural Research, Education and Extension Organization (AREEO), Karaj, Iran
2 Food Science and Technology Department, Food Science and Technology Faculty, Science and Research Branch, Islamic Azad University, Tehran, Iran
3 Food Process Engineering Department, Food Science Faculty, Gorgan University of Agricultural Sciences & Natural Resources, Gorgan, Iran
Abstract
To apply the nanomaterial as a component in the packaging material structure, in this research, the carboxymethyl cellulose (CMC)/polyvinyl alcohol (PVA) film were prepared with three levels of nanoclay particles (0.5, 1 and 3%) using solution casting evaporation method. The incorporation of nanoclay on mechanical, water vapor permeability, and oxygen barrier properties of CMC/PVA-based film was investigated. The best result was obtained through the nanocomposite film contain 3% nanoclay. In the next step, the CMC/PVA/nanoclay films were employed for walnut packaging. After 90 days storage in the environmental condition, the optimum result was found through the nanocomposite film with 3% nanoclay in terms of oil content, moisture content, acidity and peroxide indexes of walnuts. According to the overall results, the reinforcement of CMC/PVA film with 3% nanoclay could be introduced as a good candidate for the development of high barrier food packaging material against the diffusion of water vapor and oxygen permeability.
Keywords
Main Subjects
- De Azeredo HM (2009) Nanocomposites for food packaging applications. Food Res Int 42: 1240– 1253
- Tajeddin B (2015) Natural nano-based polymers for packaging applications, In: "Eco-friendly polymer nanocomposites: chemistry and applications", Thakur VK, Thakur MK (Eds.), Springer, 239-277
- Chan ML, Lau KT, Wong TT, Ho MP, Hui D (2011) Mechanism of reinforcement in a nanoclay/polymer composite. Compose Part B-Eng 42: 1708–1712
- Majdzadeh Ardakani K, Navarchian AH, Sadeghi F (2010) Optimization of mechanical properties of thermoplastic starch/clay nanocomposites. Carbohydr Polym 79: 547- 554
- Park HM, Lee WK, Park CY, Cho WJ, Ha CS (2003) Environmentally friendly polymer hybrids. J Mater Sci 38(5): 909-915
- Ray SS, Bousima M (2005) Biodegradable polymers and their layered silicate nanocomposites: in greening the 21st century materials world. Prog Mater Sci 50: 962-1079
- Ray SS (2010) A New possibility for microstructural investigation of clay-based polymer nanocomposite by focused ion beam tomography. Polymer 51: 3966-3970
- Taghizadeh MT, Sabouri N (2013) Thermal degradation behavior of polyvinyl alcohol/starch/ carboxymethyl cellulose/clay nanocomposites. Universal J Chem 1: 21-29
- Chivrac F, Gueguen O, Pollet E, Ahzi S, Makradi A, Averous L (2008) Micromechanical modeling and characterization of the effective properties in starch based nano-biocomposites. Acta Biomater 4: 1707-1714
- Cyras VP, Manfredi LB, Ton-That M, Vazquez A (2008) Physical and mechanical properties of thermoplastic starch/montmorillonite nanocomposite films. Carbohydr Polym 73: 55-63
- Almasi H, Ghanbarzadeh B, Entezami AA (2010) Physicochemical properties of starch-CMCnanoclay biodegradable films. Int J Biol Macromol 46: 1-5
- Ma X, Chang PR, Yu J (2008) Properties of biodegradable thermoplastic pea starch/carboxymethyl cellulose and pea starch/microcrystalline cellulose composites. Carbohydr Polym 72: 369- 375
- Abolghasemi Fakhri L, Ghanbarzadeh B, Dehghannia J, Entezami AA (2012) The effects of montmorillonite and cellulose nanocrystals on physical properties of carboxymethyl cellulose/ polyvinyl alcohol blend films. Iran J Polym Sci Technol 24: 455-466
- Taghizadeh MT, Sabouri N, Ghanbarzadeh B (2013) Polyvinyl alcohol/starch/ carboxymethyl cellulose containing sodium montmorillonite clay blends; mechanical properties and biodegradation behavior. Springer Plus 2: 376
- Lee SY, Mohan DJ, Kang IA, Doh GH, Lee S, Han SO (2009) Nanocellulose reinforced PVA composite films: Effects of acid treatment and filler loading. Fiber Polym 10: 77-82
- Chillo S, Flores S, Mastromatteo M, Conte M, Gershenson L, Del Nobile MA (2008) Influence of glycerol and chitosan on tapioca starch-based edible film properties. J Food Eng 88: 159-168
- Galus S, Uchanski P, Lenart A (2013) Colour, mechanical properties and water vapour permeability of pectin films. Acta Agrophys 20: 375-384
- Vanin FM, Sobral PJA, Menegalli FC, Carvalho RA, Habitante AMQB (2005) Effects of plasticizers and their concentrations on thermal and functional properties of gelatin-based films. Food Hydrocoll 19: 899-907
- Fatima T, Showkat U, Hussain SZ (2018) Nutritional and health benefits of walnuts. J Pharmacogn Phytochem 7: 1269-1271
- Poggetti L, Ferfuia C, Chiaba C, Testolin R, Baldini M (2018) Kernel oil content and oil composition in walnut (Juglans regia L.) accessions from north-eastern Italy. J Sci Food Agric 98: 955-962
- Jensen PN, Sørensen G, Brockhoff P, Bertelsen G (2003) Investigation of packaging systems for shelled walnuts based on oxygen absorbers. J Agric Food Chem 51: 4941–4947
- Baldwin EA (2006) Use of edible coating to preserve pecans at room temperature. Hortic Sci 41: 188-192
- Anonymous (2002) Standard test methods for tensile properties of thin plastic sheeting. American Society for Testing and Material ASTM 882-02
- Anonymous (2000) Standard test method for water vapor transmission of materials. American Society for Testing and Material ASTM E00996-00
- Ou S, Wang Y, Tang S, Huang C, Jackson MG (2005) Role of ferulic acid in preparing edible films from soy protein isolate. J Food Eng 70: 205-210
- Anonymous (2018) Animal and vegetable fats and oils- determination of peroxide value- Iodometric (visual) endpoint determination. Irannian National Standardization Organization INSO4179, 2nd Revision, Identical with ISO 960:2017
- Anonymous (2005) Official method of analysis (17th Ed). Association of Official Analytical (AOAC)
- Hamilton RJ, Rossell JB (1986) Analysis of oils and fats. Elsevier Applied Science Publishers
- Anonymous (2011) Animal and vegetable fats and oils -determination of acid value and acidity test method. Irannian National Standardization Organization INSO-4178
- Tajeddin B, Ramedani N (2016) Preparation and characterization (mechanical and water absorp - tion properties) of CMC/PVA/clay nanocompos - ite films. Iran J Chem Chem Eng 35: 9-15
- Ray SS, Pouliot S, Bousmina M, Utracki LA (2004) Role of organically modified layered sili - cate as an active interfacial modifier in immis - cible polystyrene/polypropylene blends. Polymer 45: 8403–8413
- Müller CMO, Laurindo JB, Yamashita F (2012) Composites of thermoplastic starch and nano - clays produced by extrusion and thermopressing. Carbohydr Polym 89: 504-510
- Rhim J, Ng P (2007) Natural biopolymer-based nanocomposite films for packaging applications. Crit Rev Food Sci Nutr 47: 411-433
- Vasconez MB, Flores SK, Campos CA, Alvarado J, Gerschenson LN (2009) Antimicrobial activ - ity and physical properties of chitosan- tapioca starch based edible films and coating. Food Res Int 42: 762-769
- Tang X (2008) Use of extrusion for synthesis of starch clay nanocomposites for biodegradable packaging films. PhD Thesis, Food Science Insti - tute, College of Agriculture, Kansas State Univer - sity, Manhattan, USA
- Ray SS, Quek SY, Easteal A, Chen XD (2006) The potential use of polymer-clay nanocompos - ites in food packaging. Int J Food Eng 2: 1556- 3758
- Tajeddin B (2004) The effect of polymer films on walnut packaging. Agronomy and Horticulture www.agris.fao.org
- Tang X, Alavi S, Herald TJ (2008) Barrier and mechanical properties of starch-clay nanocom - posite films. Cereal Chem 85: 433-439
- Adame D, Beall G (2009) Direct measurement of the constrained polymer region in polyamide/clay nanocomposites and the implications for gas diffusion. Appl Clay Sci 42: 545-552
- Chakrabarty MM (2003) Chemistry and technol - ogy of oils and fats. Allied Publishers Pvt. Ltd