Study on the fouling behavior of HDPE/PE-g-MA/EVA blend membrane fabricated via thermally induced phase separation method

Document Type : Original research


1 Membrane Technology Research Center, Sahand University of Technology, Tabriz, Iran

2 Faculty of Chemical Engineering, Sahand University of Technology, Tabriz, Iran


In this study, neat HDPE and HDPE/PE-g-MA/EVA blend membranes were fabricated via thermally induced phase separation (TIPS) method and their fouling behaviors were examined using filtration of BSA protein. Membranes were characterized using FESEM, AFM, ATR-FTIR analyses and porosity measurement. Fouling behavior of membranes was analyzed using the resistance-in-series (RIS), classic and combined pore blocking models. The results of RIS model revealed that the magnitude of inherent, reversible and irreversible resistances decreased from 0.611 ×1013m-1 and ,1.578 ×1013m-1 and 0.525 ×1013m-1 for the neat membrane to 0.237 ×1013m-1, 0.789 ×1013m-1 and 0.154×1013m-1 for the blend membrane, respectively. None of the classical Hermia’s models were able to accurately predict fouling during the entire filtration run. The results obtained from the combined pore blocking model indicated that the combined cake formation-intermediate blocking model provided good prediction of fouling mechanism for both the membranes. However, comparison between fitted parameters showed that much greater fouling occurred for pure HDPE membrane. The key reasons for such different fouling behaviors were mainly attributed to the difference in hydrophobicity as well as the distribution of pore size on the surface of the pure and blend membranes.


Main Subjects


    1. Bertin D, Leblanc M, Marque SRA, Siri D (2010) Polypropylene degradation: Theoretical and experimental investigations. Polym Degrad Stabil 95: 782-791
    2. Gugumus F (2002) Re-examination of the thermal oxidation reactions of polymers 3. Various reactions in polyethylene and polypropylene. Polym Degrad Stabil 77: 147-155
    3. Ying Q, Zhao Y, Liu Y(1991) A study of thermal oxidative and thermal mechanical degradation of polypropylene. Makromol Chem 192: 1041-1058
    4. Wang X, Wang B, Song L, Wen P, Tang G, Hua Y (2013) Antioxidant behavior of a novel sulfur- bearing hindered phenolic antioxidant with a high molecular weight in polypropylene. Polym Degrad Stabil 98: 1945-1951
    5. Voigt W, Todesco R (2002) New approaches to the melt stabilization of polyolefins. Polym Degrad Stabil 77: 397-402
    6. Richaud E, Fayolle B, Verdu J (2011) Polypropylene stabilization by hindered phenols- Kinetic aspects. Polym Degrad Stabil 96: 1-11
    7. Allen N S, Edge M (1992) Fundamentals of polymer degradation and stabilization.3rd ed., Elsevier, 22-51
    8. Marques M, Oliveira R, Araujo R, Amantes B (2014) In situ stabilization of polypropylene by lignin using a Ziegler-Natta catalyst. Polyolefins J 1: 17-24
    9. Kim T H, Oh DR (2004) Melt grafting of maleimides having hindered phenol antioxidant onto low molecular weight polyethylene. Polym Degrad Stabil 84: 499-503
    10. Shi X, Wang J, Jiang B, Yang Y (2013) Hindered phenol grafted carbon nanotubes for enhanced thermal oxidative stability of polyethylene. Polymer 54: 1167-1176
    11. Jahanmardi R, Assempour H (2008) Effects of galbanic acid on thermal and thermo-oxidative stabilities of LLDPE. Iran Polym J 17: 799-806
    12. Sabnis RW (2007) Handbook of acid-base indicators. CRC Press, 361-390
    13. Abbehausen C, Formiga ALB, Sabadini E, Yoshida IVP (2010) A β-cyclodextrin/siloxane hybrid polymer: Synthesis, characterization and inclusion complexes. J Braz Chem Soc 21: 1867- 1876
    14. Jahanmardi R, Pourattar P, Soleimani H, Shohani N (2016) Effects of thymolphthalein on thermo- oxidative stability of high density polyethylene in melt and solid states. Int J Ind Chem, in press
    15. Yang R, Liu Y, Yu J, Wang K (2006) Thermal oxidation products and kinetics of polyethylene composites. Polym Degrad Stabil 91: 1651-1657
    16.  Zeynalov E B, Allen N S (2006) Modelling light stabilizers as thermal antioxidants. Polym Degrad Stabil 91: 3390-3396
    17. Mohammadhosseini M, Jahanmardi R (2014) Investigating effect of ferric stearate on stabilization efficiency of a phenolic antioxidant during thermal oxidation of polyethylene. Iran Polym J 23: 801-807
    18. Ma Z, Wen X, Zhao F, Xia Y, Huang X, Waite D, Guan J (2013) Effect of temperature variation on membrane fouling and microbial community structure in membrane bioreactor. Bioresource Technol 133: 462-468
    19. Sim S, Taheri A, Chong T, Krantz W, Fane A (2014) Colloidal metastability and membrane fouling–Effects of crossflow velocity, flux, salinity and colloid concentration. J Membrane Sci 469: 174-187
    20. Mourouzidis-Mourouzis S, Karabelas A (2006) Whey protein fouling of microfiltration ceramic membranes—pressure effects. J membrane Sci 282: 124-132
    21. Behboudi A, Jafarzadeh Y, Yegani R, Akbari A (2017) Preparation and characterization of polyethylene/glass fiber composite membrane prepared via thermally induced phase separation method. Polyolefins J 4:199-210
    22. Fonouni M, Yegani R, Anarjani S, Tavakoli A (2016) Anti-fouling behaviors of surface functionalized high density polyethylene membrane in microfiltration of bovine serum albumin protein. Polyolefins J 4: 13-26
    23. Abdelrasoul A, Doan H, Lohi A (2013) A mechanistic model for ultrafiltration membrane fouling by latex. J Membrane Sci 433: 88-99
    24. Yuan W, Zydney AL (1999) Humic acid fouling during microfiltration. J Membrane Sci 157: 1-12
    25. Jafarzadeh Y, Yegani R (2015) Thermal, mechanical, and structural properties of ZnO/polyethylene membranes made by thermally induced phase separation method. J Appl Polym Sci 132 (30): 42337
    26. Jafarzadeh Y, Yegani R, Tantekin‐Ersolmaz S (2015) Effect of TiO2 nanoparticles on structure and properties of high density polyethylene membranes prepared by thermally induced phase separation method. Polym Adv Technol 26: 392-398
    27. Kang S, Asatekin A, Mayes AM, Elimelech M (2007) Protein antifouling mechanisms of PAN UF membranes incorporating PAN-g-PEO additive. J Membrane Sci 296: 42-50
    28. Rajabzadeh S, Maruyama T, Ohmukai Y, Sotani T, Matsuyama H (2009) Preparation of PVDF/PMMA blend hollow fiber membrane via thermally induced phase separation (TIPS) method. Separ Purif Technol 66: 76-83
    29. Shokri E, Yegani R, Heidari S, Shoeyb Z (2015) Effect of PE-g-MA compatibilizer on the structure and performance of HDPE/EVA blend membranes fabricated via TIPS method. Chem Eng Res Des 100: 237-247
    30. Chang I-S, Field R, Cui Z (2009) Limitations of resistance-in-series model for fouling analysis in membrane bioreactors: A cautionary note. Desalin Water Treat 8: 31-36
    31. Chang I-S, Kim S-N (2005) Wastewater treatment using membrane filtration—effect of biosolids concentration on cake resistance. Process Biochem 40: 1307-1314
    32. Gésan-Guiziou G, Boyaval E, Daufin G (1999) Critical stability conditions in crossflow microfiltration of skimmed milk: transition to irreversible deposition. J Membrane Sci 158: 211-222
    33. Hermans P, Bredée H (1936) Principles of the mathematical treatment of constant-pressure filtration. J Soc Chem Ind 55: 1-4
    34. Jafarzadeh Y, Yegani R (2015) Analysis of fouling mechanisms in TiO2 embedded high density polyethylene membranes for collagen separation. Chem Eng Res Des 93: 684-695
    35. Bolton G, LaCasse D, Kuriyel R (2006) Combined models of membrane fouling: development and application to microfiltration and ultrafiltration of biological fluids. J Membrane Sci 277: 75-84
    36. Akbari A, Yegani R, Razavi M, Alikhani M (2011) Preparation of high density polyethylene (HDPE) membranes via thermally induced phase separation. In: Proceeding of the 7th international chemical engineering congress and exhibition
    37. Mansourizadeh A, Azad AJ (2014) Preparation of blend Polyethersulfone/cellulose acetate/poly-ethylene glycol asymmetric membranes for oil–water separation. J Polym Res 21: 1-9
    38. Jafarzadeh Y, Yegani R, Sedaghat M (2014) Preparation, characterization and fouling analysis of ZnO/polyethylene hybrid membranes for collagen separation. Chem Eng Res Des 94: 417-427
    39. Majid RA, Ismail H, Taib RM (2010) Effects of polyethylene-g-maleic anhydride on properties of low density polyethylene/thermoplastic sago starch reinforced kenaf fibre composites. Iran Polym J 19: 501-510
    40. Lalia BS, Kochkodan V, Hashaikeh R, Hilal N (2013) A review on membrane fabrication: Structure, properties and performance relationship. Desalination 326: 77-95
    41. Nghiem LD, Hawkes S (2009) Effects of membrane fouling on the nanofiltration of trace organic contaminants. Desalination 236: 273-281
    42. Yunos MZ, Harun Z, Basri H, Ismail AF (2014) Studies on fouling by natural organic matter (NOM) on polysulfone membranes: Effect of polyethylene glycol (PEG). Desalination 333: 36-44
    43. Amin INHM, Mohammad AW, Markom M, Peng LC, Hilal N (2010) Analysis of deposition mechanism during ultrafiltration of glycerin-rich solutions. Desalination 261: 313-320
    44. Vela MCV, Blanco SA, García JL, Rodríguez EB (2008) Analysis of membrane pore blocking models applied to the ultrafiltration of PEG. Separ Purif Technol 62: 489-498
    45. Siddiqui MU, Arif AFM, Bashmal S (2016) Permeability-selectivity analysis of microfiltration and ultrafiltration membranes: Effect of pore size and shape distribution and membrane stretching. Membranes 6: 40
    46. Donovan R.P. (1985) Fabric filtration for combustion sources, CRC Press, New York, NY
    47. Liu SH, Xu ZL, Liu M, Wei YM, Guo F (2017) Preparation and characterization of PES/CA microporous membranes via reverse thermally induced phase separation process. Polym Eng Sci, In Press, DOI: 10.1002/pen.24545
    48. Zhang Q, Lu X, Zhao L (2014) Preparation of polyvinylidene fluoride (PVDF) hollow fiber hemodialysis membranes. Membranes 4: 81-95