Preparation and characterization of polyethylene/ glass fiber composite membrane prepared via thermally induced phase separation method

Document Type: Original research


1 Faculty of Chemical Engineering, Sahand University of Technology, Tabriz, Iran

2 Membrane Technology Research Center, Sahand University of Technology, Tabriz, Iran


Grinded glass fiber (GGF) embedded high density polyethylene (HDPE) membranes were prepared via thermally induced phase separation method. FESEM images showed that all the membranes had leafy structure, indicating a solid-liquid mechanism during phase separation. The results of EDX and TGA analyses confirmed that the fibers were dispersed in the HDPE matrix uniformly. Normalized water flux of the membranes increased from 1 for the neat HDPE membrane to more than 4 for 10 wt% GGF/HDPE membrane. Moreover, the contact angle decreased from 129° to 94° as the GGF content increased in the membranes, showing an improvement in the surface hydrophilicity of the membranes. The AFM results revealed that the surface roughness of the membranes was increased with increasing the GGF content. The results of abrasion test revealed that the GGF/HDPE membranes had a more abrasion resistance than the neat HDPE membrane. Finally, the fouling behavior of the membranes was investigated by the filtration of BSA protein solution and the results showed that with increasing the glass fiber content, total fouling ratio decreased from 90% for the neat HDPE membrane to 62% for 10 wt% GGF/HDPE membrane, indicating that the antifouling properties of the membranes were improved due to the presence of glass fiber.


  1. Balta S, Sotto A, Luis P, Benea L, Van der Brug­gen B, Kim J (2012) A new outlook on membrane enhancement with nanoparticles: The alternative of ZnO. J Membrane Sci 389: 155-161
  2. Hilal N, Ogunbiyi OO, Miles NJ, Nigmatullin R (2005) Methods employed for control of fouling in MF and UF membranes: A comprehensive re­view. Separ Sci Technol 40: 1957-2005
  3. Hoek EMV, Ghosh AK, Huang X, Liong M, Zink JI (2011) Physical-chemical properties, separation performance, and fouling resistance of mixed-matrix ultrafiltration membranes. Desali­nation 283: 89-99
  4. Van der Bruggen B, Braeken L, Vandecasteele C (2002) Flux decline in nanofiltration due to ad­sorption of organic compounds. Sep Purif Tech­nol 29: 23-31
  5. Van der Bruggen B, Manttari M, Nystrom M (2008) Drawbacks of applying nanofiltration and how to avoid them: A review. Sep Purif Technol 63: 251-263
  6. Ulbricht M (2006) Advanced functional polymer membranes. Polymer 47: 2217-2262
  7. Liang S, Xiao K, Mo Y, Huang X (2012) A novel ZnO nanoparticle blended polyvinylidene fluo­ride membrane for anti-irreversible fouling. J Membrane Sci 394: 184-192
  8. Jafarzadeh Y, Yegani R (2015) Analysis of foul­ing mechanisms in TiO2 embedded high density polyethylene membranes for collagen separation. Chem Eng Res Des 93: 684-695
  9. Rahimpour A, Madaeni SS, Taheri AH, Man­sourpanah Y (2008) Coupling TiO2 nanoparticles with UV irradiation for modification of polyether­sulfone ultrafiltration membranes. J Membrane Sci 313: 158-169
  10. Ulbricht M, Belfort G (1996) Surface modifica­tion of ultrafiltration membranes by low tempera­ture plasma II. Graft polymerization onto polyac­rylonitrile and polysulfone. J Membrane Sci 111: 193-215
  11. De Sitter K, Dotremont C, Genne I, Stoops L (2014) The use of nanoparticles as alternative pore former for the production of more sustain­able polyethersulfone ultrafiltration membranes. J Membrane Sci 471: 168-178
  12. Shi F, Ma Y, Ma J, Wang P, Sun W (2012) Prepa­ration and characterization of PVDF/TiO2 hybrid membranes with different dosage of nano-TiO2. J Membrane Sci 389: 522-531
  13. Behboudi A, Jafarzadeh Y, Yegani R (2016) Prep­aration and characterization of TiO2 embedded PVC ultrafiltration membranes. Chem Eng Res Des 114: 96-107
  14. Etemadi H, Yegani R, Babaeipour V (2016) Study on the reinforcing effect of nanodiamond parti­cles on the mechanical, thermal and antibacterial properties of cellulose acetate membranes. Dia­mond Relat Mater 69: 166-176
  15. Cui A, Liu Z, Xiao C, Zhang Y (2010) Effect of micro-sized SiO2-particle on the performance of PVDF blend membranes via TIPS. J Membrane Sci 360: 259-264
  16. Safarpour M, Khataee A, Vatanpour V (2015) Thin film nanocomposite reverse osmosis mem­brane modified by reduced graphene oxide/TiO2 with improved desalination performance. J Mem­brane Sci 489: 43-54
  17. Zhang J, Xu Z, Shan M, Zhou, Li Y, Li B, Niu J, Qian X (2013) Synergetic effects of oxidized carbon nanotubes and graphene oxide on fouling control and anti-fouling mechanism of polyvinyl­idene fluoride ultrafiltration membranes. J Mem­brane Sci 448: 81-92
  18. Wang L, Song X, Wang T, Wang S, Wang Z, Gao C, (2015) Fabrication and characterization of polyethersulfone/carbon nanotubes (PES/CNTs) based mixed matrix membranes (MMMs) for nanofiltration application. Appl Surf Sci 330: 118-125
  19. Zhang Q, Veciti CD, (2014) Conductive CNT-PVDF membrane for capacitive organic fouling reduction. J Membrane Sci 459: 143-156
  20. Rabiee H, Vatanpour V, Davood Abadi Farah­ani MH, Zarrabi H, (2015) Improvement in flux and antifouling properties of PVC ultrafiltration membranes by incorporation of zinc oxide (ZnO) nanoparticles. Sep Purif Technol 156: 299–310
  21. Xi Z-Y, Xu Y-Y, Zhu L-P, Du C-H, Zhu B-K (2008) Effect of stretching on structure and prop­erties of polyethylene hollow fiber membranes made by melt-spinning and stretching process. Polym Advan Technol 19: 1616-1622
  22. Zhang C, Bai Y, Sun Y, Gu J, Xu Y (2010) Prepa­ration of hydrophilic HDPE porous membranes via thermally induced phase separation by blend­ing of amphiphilic PE-b-PEG copolymer. J Mem­brane Sci 365: 216-224
  23. Kolesov IS, Kratz K, Lendlein A, Radusch H-J(2009) Kinetics and dynamics of thermally-induced shape-memory behavior of crosslinked short-chain branched polyethylenes. Polymer 50: 5490-5498
  24. Park MJ, Kim CK (2014) Fabrication of polyeth­ylene microporous membranes using triethylol­propane tris(2-ethylhexanoate) as a novel diluent by a thermally induced phase separation process. J Membrane Sci 449: 127-135
  25. Mosadegh-Sedghi S, Rodrigue D, Brisson J, Ili­uta MC (2013) Highly hydrophobic microporous low-density polyethylene hollow fiber mem­branes by melt-extrusion coupled with salt-leach­ing technique. Polym Adv Technol 24: 584-592
  26. Liu J-H, Jen H-L, Chung Y-C (1999) Surface modification of polyethylene membranes using phosphorylcholine derivatives and their platelet compatibility. J Appl Polym Sci 74: 2947-2954
  27. Zhang J, Jiang DD, Wilkie CA (2006) Polyethyl­ene and polypropylene nanocomposites based on a three component oligomerically-modified clay. Polym Degrad Stabil 91: 641-648
  28. Zhang J, Jiang DD, Wilkie CA (2005) Polyeth­ylene and polypropylene nanocomposites based upon an oligomerically modified clay. Thermo­chim Acta 430: 107-113
  29. Jafarzadeh Y, Yegani R, Sedaghat M (2015) Prep­aration, characterization and fouling analysis of ZnO/polyethylene hybrid membranes for colla­gen separation. Chem Eng Res Des 94: 417-427
  30. Jafarzadeh Y, Yegani R (2015) Thermal, mechan­ical, and structural properties of ZnO/polyethyl­ene membranes made by thermally induced phase separation method. J Appl Polym Sci 132: 42338
  31. Jafarzadeh Y, Yegani R, Tantekin-Ersolmaz SB (2015) Effect of TiO2 nanoparticles on structure and properties of high density polyethylene mem­branes prepared by thermally induced phase sep­aration method. Polym Advan Technol 26: 392- 398
  32. Peyki A, Rahimpour A, Jahanshahi M (2015) Preparation and characterization of thin film com­posite reverse osmosis membranes incorporated with hydrophilic SiO2 nanoparticles. Desalination 368: 152-158
  33. Ghandashtani MB, Zokaee Ashtiani F, Karimi M, Fouladitajar A (2015) A novel approach to fabri­cate high performance nano-SiO2 embedded PES membranes for microfiltration of oil-in-water emulsion. Appl Surf Sci 349: 393-402
  34. Efome JE, Baghbanzadeh M, Rana D, Matsuura T, Lan CQ (2015) Effects of superhydrophobic SiO2 nanoparticles on the performance of PVDF flat sheet membranes for vacuum membrane dis­tillation. Desalination 373: 47-57
  35. Luo N, Xu R, Yang M, Yuan X, Zhong H, Fan Y (2015) Preparation and characterization of PVDF-glass fiber composite membrane rein­forced by interfacial UV-grafting copolymeriza­tion, J Environ Sci 38: 24-35
  36. Lai CY, Groth A, Gray S, Duke M (2014) En­hanced abrasion resistant PVDF/nanoclay hollow fiber composite membranes for water treatment. J Membrane Sci 449: 146-157
  37. Lloyd DR, Kinzer KE, Tseng HS (1990) Micropo­rous membrane formation via thermally induced phase separation. I. Solid-liquid phase separation. J Membrane Sci 52: 239-261
  38. Razmjou A, Mansouri J, Chen V (2011) The ef­fects of mechanical and chemical modification of TiO2 nanoparticles on the surface chemistry, structure and fouling performance of PES ultra­filtration membranes. J Membrane Sci 378: 73-84
  39. Zuo X, Wang L, He J, Li Z, Yu S (2014) SEM-EDX studies of SiO2/PVDF membranes fouling in electrodialysis of polymer-flooding produced wastewater: Diatomite, APAM and crude oil. De­salination 347: 43-51
  40. Kebria MRS, Jahanshahi M, Rahimpour A (2015) SiO2 modified polyethyleneimine-based nanofil­tration membranes for dye removal from aqueous and organic solutions. Desalination 367: 255-264
  41. Nguyen VG, Thai H, Mai DH, Tran HT, Tran DL, Vu MT (2013) Effect of titanium dioxide on the properties of polyethylene/TiO2 nanocomposites. Composites Part B- Eng 45: 1192-1198