Morphology control of clay-mineral particles as supports for metallocene catalysts in propylene polymerization

Document Type : Original research

Authors

1 Research and Development Division, Japan Polychem Corporation, 1, Toho-cho Yokkaichi, Mie 510-0848, Japan

2 Graduate school of Engineering, Hokkaido University, Kita 13, Nishi 8, Kita-ku, Sapporo, 060-8628, Japan

Abstract

Spray dry granulation of clay minerals was studied to obtain clay mineral base support material for metallocene supported olefin polymerization catalysts. The morphology of the granules was strongly influenced by the nature of the clay mineral itself.
Because of swelling characteristics of montmorillonite, its water dispersion was highly viscous even in the low slurry concentration (< 4 wt %). Therefore, it was very difficult to control the granule characteristics such as size, shape, and inside structure by the spray dry with the clay mineral slurry. Then we examined some methods in order to change the clay mineral surface properties for getting less viscous dispersion.
It was found that the milling of montmorillonite increased the amount of surface OH groups. This surface characteristic change should promote the interaction between the edges and basal planes of the primary particles of milled montmorillonite, resulting in the lowering the slurry viscosity. The milling is effective for overcoming difficulty in use of high concentration montmorillonite slurry in spray dry granulation which is indispensable for producing granules in the wide range of size (10–50 μm).
The spray-dried montmorillonite granules are useful as a "Support-Activator" for an olefin polymerization catalyst combined with metallocenes.

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Main Subjects

References

  1. Floyd S, Heiskane T, Taylor TW, Mann GE, Ray WH (1987) Polymerization of olefins through heterogeneous catalysis. VI. Effect of particle heat and mass transfer on polymerization behavior andpolymer properties. J Appl Polym Sci 33: 1021-1065
  2. Hutchinson RA, Chen CM, Ray WH (1992) Polymerization of olefins through heterogeneous catalysis X: Modeling of particle growth and morphology. J Appl Polym Sci 44: 1389-1414
  3. Kakugo M, Sadatoshi H, Sakai J, YokoyamaM (1989) Growth of polypropylene particles in heterogeneous Ziegler-Natta polymerization. Macromolecules 22: 3172-3177
  4. Galli P, Haylock JC (1991) Continuing initiator system developments provide a new horizon for polyolefin quality and properties. Prog Polym Sci 16: 443-462
  5. Edward P, Moore JR (1996) Catalysts and polymerizations. In: Polypropylene handbook, Hanser/Grandner publications, Inc., Cincinnati, 11-45
  6. Bernard A, Fiasse P (1990) Catalytic olefin polymerization. Kodansha Ltd., 405-423
  7. Pasquon I, Giannini U (1984) Catalysis science and technology Vol.6, Chapter 2, Springer Verlag, New York, Tokyo
  8. Ewen JA, Johnes RL, Razavi A, Ferrara JD (1988) Syndiospecific propylene polymerizations with Group IVB metallocenes. J Am Chem Soc 110: 6255-6256
  9. Sugano T, Tayano T, Uchino H, Ioku A, Iwama N, Endo J, Osano Y (1999) Novel metallocene catalyst for propylene polymerization. In: SPO99. Houston, USA
  10. Cai Z, Nakayama Y, Shiono T (2006) Living random copolymerization of propylene and norbornene with ansa-Fluorenyl amido dimethyl titanium complex: Synthesis of novel syndiotactic polypropylene-b-poly (propyleneran- norbornene). Macromolecules 39: 2031-2033
  11. Hlatky GG, Turner HW, Eckman RR (1989) Ionic, base-free zirconocene catalysts for ethylene polymerization. J Am Chem Soc 111: 2728-2729
  12. Yang X, Stern CL, Marks TJ (1991) Cationlike homogeneous olefin polymerization catalysts based upon zirconocene alkyls and tris(pentafluorophenyl) borane. J Am Chem Soc 113: 3623-3625
  13. Kioka M, Toyota A, Kashiwa N, Tsutsui T (2000 May 16) Catalyst for polymerizing alpha-olefins and process for polymerization. US Patent 6,063,726
  14. Ewen JA, Welborn HCJR (1985 July 23) Process and catalyst for producing polyethylene having a broad molecular weight distribution. US Patent 4,530,914
  15. Chien JCW, He D (1991) Olefin copolymerization with metallocene catalysts. III. Supported metallocene/methylaluminoxane catalyst for olefin copolymerization. J Polym Sci A: Polym Chem 29: 1603-1607
  16. Kaminsky W (1995) How to reduce the ratio MAO/metallocene. Macromol Symp 97: 79-89
  17. Suga Y, Maruyama Y, Isobe E, Suzuki T, Shimizu F (1994 May 3) Catalyst for polymerizing an olefin and method for producing an olefin polymer. US Patent 5,308,811
  18. Weiss K, Wirth-Pfeifer C, Hoffmann M, Botzenhardt S, Lang H, Bruning K, Meichel E (2002) Polymerization of ethylene or propylene with heterogeneous metallocene catalysts on the clay. J Mol Catal A: Chem 182-183: 143-149
  19. Sano T, Niimi T, Miyazaki T, Tsubaki S, Oumi Y, Uozumi T (2001) Effective activation of metallocene catalyst with AlMCM-41 in propylene polymerization. Catal Lett 71: 105-110
  20. Takahashi T, Nakano H, Uchino H, Tayano T (2002) Study of the clay mineral “ supportactivator” in metallocene catalyst. Poym Prep 43: 1259
  21. Suga Y, Isobe E, Suzuki T, Fujioka K, Ishihama Y, Sagae T, Go S, Uehara Y (1999) Novel clay mineral-supported metallocene catalysts for olefin polymerization. In: MetCon’99 polymers in transition, Houston, USA
  22. Tayano T, Sugawara M (2000) Advanced metallocene technology for propylene random copolymer. In: MetCon’2000 Polymers in transition, Houston, USA
  23. Sugano T, Iwama N, Isobe E, Suzuki T, Maruyama Y, Hayakawa A, Shoda H, Kashimoto M, Kato T, Aoshima T, Nishimura A, Suga Y, Sieber S (1999 May 20) Transition metal compounds. US Patent Appl. No. 09/315,131
  24. Uchino H, Itoh M, Ishihama Y, Nakano M (2010 Oct 6) Propylene-based polymer, production method therefor, composition using the same, and application thereof. JP Patent 4,558,066
  25. Fukushi K, Suzuki M (2004) Surface complexation modeling of the acid/base chemistry of natural allophane. J Clay Sci Soc 43: 180-185
  26. Rozalen M, Brady PV, Huertas FJ (2009) Surface chemistry of K-montmorillonite: Ionic strength, temperature dependence and dissolution kinetics. J Colloid Interf Sci 333: 474-484
  27. Japan Industrial Standard (2010) Plasticspolypropylene (PP) molding and extrusion materials- Part 2: Preparation of test specimens and determination of properties. JIS K6921-2
  28. American society for testing and materials (2010) Standard test methods for apparent density, bulk factor, and pourability of plastic materials. ASTM D1895-96
  29. Tsutsui T, Ishimaru N, Mizuno A, Toyota A., Kashiwa N (1989) Propylene homo- and copolymerization with ethylene using an ethylenebis(1-indenyl)zirconium dichloride and methylaluminoxane catalyst system. Polymer 30: 1350-1356
  30. Ray GJ, Johnson PE, Knox JR, (1977) Carbon-13 nuclear magnetic resonance determination of monomer composition and sequence distribution in ethylene-propylene copolymers prepared with a streoregular catalyst system. Macromolecules 10: 773-778
  31. Fraser RP, Dombrowski N, Routley JH (1963) The atomization of a liquid sheet by an impinging air stream. Chem Eng Sci 18: 339-353
  32. Charlesworth DH, Marshall WRJR (1969) Evaporation from drops containing dissolved solids. AIChE J 6: 9-23
  33. Abend S, Lagaly G (2000) Sol-gel transion of sodium montmorillonite dispersions. Applied Clay Science 16: 201-227
  34. Armando GR, Torre L, Garcia-Serrano LA, Aguilar- Elguezbal A (2004) Effect of dialysis treatment on the aggregation state of montmorillonite clay. J Colloid Interf Sci 274: 550-554
  35. Allan K (1958) The flocculation of sodium montmorillonite by electrolytes. J Colloid Sci 13: 51-60
  36. Brandenburg U, Lagaly G (1988) Rheological properties of sodium montmorillonite dispersions. Appl Clay Sci 3: 263-279
  37. Suzuki K, Sato T, Yoneda T (2012) Factors affecting to the viscosity of montmorillonite/ water suspension 2. Relationship between aspect ratio of montmorillonite particles and viscosity of aqueous suspension. J Clay Sci Soc 50: 162-174
  38. Sagae T, Atsumi T, Uchino H, Murata M, Tayano T, Satou T (2014) Morphology control of claymineral particles as supports for metallocene catalysts in propylene polymerization. In: 58th Clay Science Forum. Fukushima, Japan
  39. Watanabe T (2009) Particle size distribution measurement. In: Handbook of clays and clay minerals, 3rd ed., Gihodobooks, Tokyo, 395-401
  40. Watanabe T (2009) XRD measurement. In: Handbook of clays and clay minerals, 3rd ed., Gihodobooks, Tokyo, 373-376
  41. Yokoyama S, Kuroda M, Sato T (2005) Atomic force microscopy study of montmorillonite dissolution under highly alkaline condition. Clays Clay Miner 53: 147-154
  42. Rozalen M, Brady PV, Huertas FJ (2009) Surface chemistry of K-montmorillonite: Ionic strength, temperature dependence and dissolution kinetics. J Colloid Interf Sci 333: 474-484
Polyolefins Journal
Volume 3, Issue 2 - Serial Number 2
Winter and Spring 2016
Pages 79-92

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History

  • Receive Date: 28 July 2015
  • Revise Date: 14 October 2015
  • Accept Date: 17 October 2015

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