Expected nucleation effects of carboxylic acid salts on poly(1-butene)

Document Type : Original research

Authors

1 College of Chemistry and Chemical Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

2 Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Engineering Plastics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China

Abstract

9,10-Dihydro-9,10-ethano-anthracene-11,12-dicarboxylic acid disodium salt (DHEAS) was synthesized and used as a nucleating agent for poly(1-butene) (iPB). The isothermal crystallization kinetics of iPB having different nucleating agents were investigated by differential scanning calorimetry (DSC) and polarized optical microscopy (POM). The results showed that the nucleating agents increased the crystallization temperature and the crystallization rate and shortened the crystallization half-time (t1/2). As well, the nucleating agents could be used as heterogeneous nuclei in the iPB matrix and decreased the size of iPB. When the nucleating agent was DHEAS, the crystallization temperature of iPB was up to 93.6°C which was higher than that of other nucleating agents for iPB and pure iPB. The crystallization half-time in the presence of DHEAS was 0.58 min which was less than that of other nucleating agents for iPB and pure iPB. In this case, the spherulitic size of iPB was the smallest and the morphology was changed, which indicated that DHEAS displayed better nucleation effect among the studied nucleating agents.

Keywords

Main Subjects


  1. Gonzalez I, Eguiazabal J, Nazabal J (2005) Compatibilization level effects on the structure and mechanical properties of rubber modified polyamide 6/clay nanocomposites. J Polym Sci B: Polym Phys 43: 3611-3620
  2. Huang J, Keskkula H, Paul D (2006) Comparison of the toughening behavior of nylon 6 versus an amorphous polyamide using various maleated elastomers. Polymer 47: 639-651
  3. Chen X, Yu J, Luo Z, Guo S, He M, Zhou Z (2011) Study on mechanical properties and phase morphology of polypropylene/polyolefin elastomer/magnesium hydroxide ternary composites. Polym Adv Technol 22: 657-663
  4. Qiu G, Liu G, Qiu W, Liu S (2013) Phase morphology and mechanical properties of polyamide-6/ polyolefin elastomer- g - maleic anhydride blends. J Macromol Sci, B 53: 615-624
  5. Choi M, Jung J-Y, Chang Y-W (2014) Shape memory thermoplastic elastomer from maleated polyolefin elastomer and nylon 12 blends. Polym Bull 71: 625-635
  6. Nishitani Y, Yamada Y, Ishii C, Sekiguchi I, Kitano T (2010) Effects of addition of functionalized SEBS on rheological, mechanical, and tribological properties of polyamide 6 nanocomposites. Polym Eng Sci 50: 100-112
  7. Isik-gulsac I, Yilmazer U, Bayram G (2013) Effects of addition order of the components on polyamide-6/ organoclay/ elastomer ternary nanocomposites. Adv Polym Technol 32: E675-E691
  8. Kohan MI, Kohan MI (1995). Nylon plastics handbook, Hanser Publishers
  9. Lincoln DM, Vaia RA, Wang ZG, Hsiao BS (2001) Secondary structure and elevated temperature crystallite morphology of nylon-6/layered silicate nanocomposites. Polymer 42: 1621-1631
  10. Maiti P, Okamoto M (2003) Crystallization controlled by silicate surfaces in nylon 6 clay nanocomposites. Macromol Mater Eng 288: 440- 445
  11. Li TC, Ma J, Wang M, Tjiu WC, Liu T, Huang W (2007) Effect of clay addition on the morphology and thermal behavior of polyamide 6. J Appl Polym Sci 103: 1191-1199
  12. Liu X,Wu Q (2002) Phase transition in nylon 6/ clay nanocomposites on annealing. Polymer 43: 1933-1936
  13. Wu TM, Liao CS (2000) Polymorphism in nylon 6/clay nanocomposites. Macromol Chem Phys 201: 2820-2825
  14. Cui L,Yeh JT (2010) Nylon 6 crystal phase transition in nylon 6/clay/poly (vinyl alcohol) nanocomposites. J Appl Polym Sci 118: 1683- 1690
  15. Chiu FC, Lai SM, Chen YL, Lee TH (2005) Investigation on the polyamide 6/organoclay nanocomposites with or without a maleated polyolefin elastomer as a toughener. Polymer 46: 11600-11609
  16. Lee KM, Han CD (2003) Rheology of organoclay nanocomposites: Effects of polymer matrix/ organoclay compatibility and the gallery distance of organoclay. Macromolecules 36: 7165-7178
  17. Xie W, Gao Z, Pan W-P, Hunter D, Singh A, Vaia R (2001) Thermal degradation chemistry of alkyl quaternary ammonium montmorillonite. Chem Mater 13: 2979-2990
  18. Brandrup J (1989) Polymer Handbook. 3rd ed. John Wiley and Sons, New York
  19. Paci M, Filippi S, Magagnini P (2010) Nanostructure development in nylon 6-Cloisite® 30B composites. Effects of the preparation conditions. Eur Polym J 46: 838-853
  20. Gomari S, Ghasemi I, Karrabi M, Azizi H (2012) Organoclay localization in polyamide 6/ethylene-butene copolymer grafted maleic anhydride blends: The effect of different types of organoclay. J Polym Res 19: 1-11
  21. Ying JR, Liu SP, Guo F, Zhou XP, Xie XL (2008) Non-isothermal crystallization and crystalline structure of PP/POE blends. J Therm Anal Calorim 91: 723-731
  22. Benderly D, Siegmann A, Narkis M (1997) Structure and behavior of multicomponent immiscible polymer blends. J Polym Eng 17: 461-490
  23. Zhang L, Wan C, Zhang Y (2008) Polyamide 6/ maleated ethylene - propylene - diene rubber/ organoclay composites with or without glycidyl methacrylate as a compatibilizer. J Appl Polym Sci 110: 1870-1879
  24. Katoh Y, Okamoto M (2009) Crystallization controlled by layered silicates in nylon 6–clay nano-composite. Polymer 50: 4718-4726
  25. Wang B, Hao L, Wang W, Hu G (2009) One-step compatibilization of polyamide 6/poly (ethylene- 1-octene) blends with maleic anhydride and peroxide. J Polym Res 17: 821-826
  26. Wahit M, Hassan A, Mohd Ishak Z, Czigány T (2009) Ethylene-octene copolymer (POE) toughened polyamide 6/ polypropylene nanocomposites: Effect of POE maleation. Express Polym Lett 3: 309-319
  27. Cervantes-Uc JM, Cauich-Rodríguez JV, Vázquez-Torres H, Garfias-Mesías LF, Paul DR (2007) Thermal degradation of commercially available organoclays studied by TGA–FTIR. Thermochim Acta 457: 92-102

 

Volume 3, Issue 1 - Serial Number 1
January 2016
Pages 37-45
  • Receive Date: 03 June 2015
  • Revise Date: 25 August 2015
  • Accept Date: 30 August 2015
  • First Publish Date: 01 January 2016