Olefin polymerization and copolymerization
Mohsen Javaheri; Mehdi Nekoomanesh; Yousef Jahani
Abstract
The concentration of ethylene and 1-butene in n-hexane as polymerization media was calculated at five different pressure levels (4, 6, 8, 10, and 12 bar) and four different 1-butene concentrations (0.13, 0.26, 0.39, and 0.52 mol/L) in n-hexane at T= 80°C using the Peng-Robinson thermodynamic equation ...
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The concentration of ethylene and 1-butene in n-hexane as polymerization media was calculated at five different pressure levels (4, 6, 8, 10, and 12 bar) and four different 1-butene concentrations (0.13, 0.26, 0.39, and 0.52 mol/L) in n-hexane at T= 80°C using the Peng-Robinson thermodynamic equation of state. Some combinations of conditions were selected to perform the copolymerization reaction in the presence of an industrial TiCl4/MgCl2 Ziegler-Natta catalyst. The forms of the synthesized products were visually and qualitatively classified as either powder or sticky. The percentage of incorporated 1-butene comonomer into the polyethylene chains was analyzed using calibrated FTIR tests. It was shown that for ethylene/1-butene concentration ratios (β) in n-hexane above approximately 1.80, the product forms as a powder. For values below 1.30 threshold, the product was sticky. Thus, this ratio could be used as a criterion for selecting the proper combination of copolymerization pressure and 1-butene concentration when aiming to achieve a powdered form of the product. It was shown that β has a strong correlation with the weight percentage of 1-butene in the final LLDPE polymer. Therefore it can be used as an accurate prediction for wt.% of incorporated 1-butene into the LLDPE chain within the studied concentration ranges with the specific catalyst system utilized.
Composites and nanocomposites
Raid Banat; Malek Aljnaid; Manal Al-Rawashdeh
Abstract
Mechanical and physical properties of various weigh percentages (0% - 40%) of olive pomace flour (OPF)-loaded linear low density polyethylene (LLDPE) in the presence of 0%, 5% and 10% coupling agent (C) were formulated and studied. Extrusion and hot press processing techniques were used to fabricate ...
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Mechanical and physical properties of various weigh percentages (0% - 40%) of olive pomace flour (OPF)-loaded linear low density polyethylene (LLDPE) in the presence of 0%, 5% and 10% coupling agent (C) were formulated and studied. Extrusion and hot press processing techniques were used to fabricate OPF/LLDPE composites. Tensile stress at yield increased by 20% with the increasing of the filler loading up to 20%; and marginally increased in the presence of the C. Whereas, the decline in the tensile strain at yield of the polymer composite improved with the increase in the C content. The modulus increased from 631 MPa for the neat LLDPE to 680, 808 and 700 MPa for the composites filled by 5%, 10% and 20% filler content, respectively. Whereas, a decrease in the given modulus (550 MPa) was observed at 40% filler loading. The modulus has shown a successive improvement upon the addition of the C with values not less than 800 MPa. The impact strength decreased with the increase in filler loading from 119 kJ/m2 for the neat LLDPE to 81, 43, 27 and 16 kJ/m2 for the 5%, 10%, 20% and 40% OPF/LLDPE samples, respectively. On the contrary, 10% C addition improved the impact strength of the composite by two folds in the case of 10 - 40% filler inclusion. The scanning electron microscopy (SEM) illustrations proved the mechanical performance of various bio-composite formulations. Water absorption of the bio-composite increased with the OPF loading, from 0.73% for the neat LLDPE to 2.6% for 40% OPF-filled polymer composite, and decreased upon increasing the C content with an average of 1.4% for all composites. Formulated by mixing cellulosic-based material OPF and LLDPE, the bio-composite demonstrated compatible physical properties and can be used as an already available cellulosic filler for the bio-composite materials.
Polyolefin degradation
Sara Zarei; Gholam-Reza Nejabat; Mohammad-Mahdi Mortazavi; Soheyl KhajehPour-Tadavani
Abstract
Varying amounts of an amorphous poly(1-hexene) (PH, Mv 1.7×106 Da) were added to an LLDPE matrix containing 3% w/w Addiflex oxo-biodegradable additive (HES-W) and extruded and converted into films. Then the effect of presence of PH was investigated on microstructure, thermal and tensile behavior ...
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Varying amounts of an amorphous poly(1-hexene) (PH, Mv 1.7×106 Da) were added to an LLDPE matrix containing 3% w/w Addiflex oxo-biodegradable additive (HES-W) and extruded and converted into films. Then the effect of presence of PH was investigated on microstructure, thermal and tensile behavior of polymer films before and after 6 weeks of ultra violet irradiation (UVR). Due to UVR, viscosity average molecular weight (Mv) of the sample without PH decreased from 9.6×104 to 4.6×103 Da and for the sample containing 3% w/w PH from 11.3×104 to 3.0×104 Da, also carbonyl index (CI) of the sample without PH increased from 0 to 28.7 while for the sample containing 3% w/w PH increased from 1.8 to 30.4. Moreover, differential scanning calorimetry (DSC) showed that crystallinity of the sample without PH increased from 34.4% to 36.9% and from 28.7% to 32.1% for the sample containing 3% w/w PH. Thermal gravimetric analysis (TGA) showed lower decomposition temperature for the samples containing PH. The elongation-at-break decreased from 723.0% to 88% for the sample without PH and from 410% to 10% for the sample containing PH. Atomic force microscopy (AFM) indicated smoother surfaces for samples containing 3% w/w PH before and after UVR. Although, the aforementioned results showed that the presence of limited amounts of PH in the LLDPE matrix deteriorated thermal and mechanical properties of the matrix, it hindered the oxo-biodegradablity of the matrix by opposing assimilation process perhaps due to high Mv and/or gelation.
